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A
M. Kumar Bisai, Ajithkumar, V. S., Gonnade, R. G., and Sen, S. S., “Access to a variety of Ge(II) and Sn(II) compounds through substitution of hypersilyl moiety”, Organometallics, vol. 40, no. 15, pp. 2651-2657, 2021.
S. Pahar, Swamy, V. S. V. S. N., Das, T., Gonnade, R. G., Vanka, K., and Sen, S. S., “Access to diverse germylenes and a six-membered dialane with a flexible beta-diketiminate”, Chemical Communications, vol. 56, no. 79, pp. 11871-11874, 2020.
S. Pahar, Karak, S., Pait, M., K. Raj, V., Vanka, K., and Sen, S. S., “Access to silicon(II)- and germanium(II)-indium compounds”, Organometallics, vol. 37, no. 7, pp. 1206-1213, 2018.
K. Gour, Pramanik, D., Dash, S. Ranjan, Tothadi, S., Vanka, K., and Sen, S. S., “Activation of the olefinic C-H bond of NHC and NHO by perimidine-based silicon and germanium compounds”, Organometallics, vol. 42, no. 15, pp. 1909-1917, 2023.
S. Yadav, Kumar, R., K. Raj, V., Yadav, P., Vanka, K., and Sen, S. S., “Amidinato germylene-zinc complexes: synthesis, bonding, and reactivity”, Chemistry-An Asian Journal, vol. 15, no. 19, pp. 3116-3121, 2020.
B
S. Yadav, Swamy, V. S. V. S. N., Gonnade, R. G., and Sen, S. S., “Benz–amidinato stabilized a monomeric calcium Iodide and a lithium calciate(II) cluster featuring group 1 and group 2 elements”, ChemistrySelect, vol. 1, no. 5, pp. 1066–1071, 2016.
S. Yadav, Dixit, R., Vanka, K., and Sen, S. S., “Beyond hydrofunctionalisation: a well-defined calcium compound catalysed mild and efficient carbonyl cyanosilylation”, Chemistry-A European Journal, vol. 24, no. 6, pp. 1269-1273, 2018.
C
V. S. V. S. N. Swamy, Pal, S., Khan, S., and Sen, S. S., “Cations and dications of heavier group 14 elements in low oxidation states”, Dalton Transactions, vol. 44, no. 29, pp. 12903-12923, 2015.
K. Balayan, Sharma, H., Vanka, K., Ravindranathan, S., Gonnade, R. G., and Sen, S. S., “On the competition between six-membered and five-membered NHC towards alane centered ring expansion”, Chemical Communications, vol. 59, no. 55, pp. 8540-8543, 2023.
S. Yadav, Saha, S., and Sen, S. S., “Compounds with low-valent p-block elements for small molecule activation and catalysis”, Chemcatchem, vol. 8, no. 3, pp. 486-501, 2016.
R. Kumar, Sharma, V., Banerjee, S., Vanka, K., and Sen, S. S., “Controlled reduction of isocyanates to formamides using monomeric magnesium”, Chemical Communications, vol. 59, no. 16, pp. 2255-2258, 2023.
V. S. V. S. N. Swamy, Parvin, N., K. Raj, V., and Sen, S. S., “C(sp(3))-F, C(sp(2))-F and C(sp(3))-H bond activation at silicon(II) centers”, Chemical Communication, vol. 53, no. 71, 2017.
S. Pahar, Kundu, G., and Sen, S. S., “Cyanosilylation by compounds with main-group elements: an odyssey”, ACS Omega, vol. 5, no. 40, pp. 25477-25484, 2020.
K. Bakthavachalam, Dutta, S., Arivazhagan, C., Raghavendra, B., Haridas, A., Sen, S. S., Koley, D., and Ghosh, S., “ Cyclometallation of a germylene ligand by concerted metalation-deprotonation of a methyl group ”, Dalton Transactions , vol. 47, no. 44, pp. 15835-15844, 2018.
D
R. Kumar, Bisai, M. Kumar, Jain, S., Vanka, K., and Sen, S. S., “Deoxygenative hydroboration of primary and secondary amides: a catalyst-free and solvent-free approach”, Chemical Communications, vol. 57, no. 81, pp. 10596-10599, 2021.
G. Kundu, Ajithkumar, V. S., Bisai, M. Kumar, Tothadi, S., Das, T., Vanka, K., and Sen, S. S., “Diverse reactivity of carbenes and silylenes towards fluoropyridines”, Chemical Communications, vol. 57, no. 36, pp. 4428-4431, 2021.
M. Kumar Bisai, Swamy, V. S. V. S. N., K. Raj, V., Vanka, K., and Sen, S. S., “Diverse reactivity of hypersilylsilylene with boranes and threecomponent reactions with aldehyde and HBpin”, Inorganic Chemistry, vol. 60, no. 3, pp. 1654-1663, 2021.
R. Bertermann, Boehnke, J., Braunschweig, H., Dewhurst, R. D., Kupfer, T., Muessig, J. H., Pentecost, L., Radacki, K., Sen, S. S., and Vargas, A., “Dynamic, reversible oxidative addition of highly polar bonds to a transition metal”, Journal of the American Chemical Society, vol. 138, no. 49, pp. 16140-16147, 2016.
E
M. Bisai, Das, T., Vanka, K., and Sen, S. S., “Easily accessible lithium compound catalyzed mild and facile hydroboration and cyanosilylation of aldehydes and ketones”, Chemical Communications, vol. 54, no. 50, 2018.
S. S. Sen and Roesky, H. W., “Efficient methods for preparing silicon compounds”, in Academic Press, 2016.
G. Kundu, Dash, S. Ranjan, Kumar, R., Vanka, K., Ghosh, A., and Sen, S. S., “Enhancing diradical character of chichibabin's hydrocarbon through fluoride substitution”, ChemPlusChem, vol. 88, no. 8, p. e202300273, 2023.
F
V. S. V. S. N. Swamy, Yadav, S., Pal, S., Das, T., Vanka, K., and Sen, S. S., “Facile access to a Ge(II) dication stabilized by isocyanides”, Chemical Communications, vol. 52, no. 50, pp. 7890-7892, 2016.
V. S. V. S. N. Swamy, Kundu, G., and Sen, S. S., “Facile activation of Si-H bond by an electrophilic carbene”, Indian Chemical Society, vol. 95, no. 7, pp. 789-793, 2018.
H
K. Gour, Bisai, M. Kumar, and Sen, S. S., “Hypersilyl substituent in heavier low-valent group 14 chemistry”, European Journal of Inorganic Chemistry, vol. 2022, no. 11, p. e202200071, 2022.
L
M. Kumar Bisai, Gour, K., Das, T., Vanka, K., and Sen, S. S., “Lithium compound catalyzed deoxygenative hydroboration of primary, secondary and tertiary amides”, Dalton Transactions, vol. 50, no. 7, pp. 2354-2358, 2021.
M. Kumar Bisai, Yadav, S., Das, T., Vanka, K., and Sen, S. S., “Lithium compounds as single site catalysts for hydroboration of alkenes and alkynes”, Chemical Communications, vol. 55, no. 78, pp. 11711-11714, 2019.
R. Kumar, Pahar, S., Chatterjee, J., Dash, S. Ranjan, Gonnade, R. G., Vanka, K., and Sen, S. S., “Luminescent magnesium complexes with intra- and inter-ligand charge transfer”, Chemical Communications, vol. 58, no. 84, pp. 11843-11846, 2022.
M
V. S. V. S. N. Swamy, Bisai, M. Kumar, Das, T., and Sen, S. S., “Metal free mild and selective aldehyde cyanosilylation by a neutral penta-coordinate silicon compound”, Chemical Communications, vol. 53, no. 51, 2017.
R. Kumar, Dutta, S., Sharma, V., Singh, P. P., Gonnade, R. G., Koley, D., and Sen, S. S., “Monomeric magnesium catalyzed alkene and alkyne hydroboration”, Chemistry-A European Journal, vol. 28, no. 56, 2022.
N
G. Kundu, Tothadi, S., and Sen, S. S., “Nucleophilic substitution at a coordinatively saturated five-membered NHC center dot haloborane centre”, Inorganics, vol. 10, no. 7, p. 97, 2022.
P
S. Pahar, Sharma, V., Tothadi, S., and Sen, S. S., “Pyridylpyrrolido ligand in Ge(II) and Sn(II) chemistry: synthesis, reactivity and catalytic application”, Dalton Transactions, vol. 50, no. 45, pp. 16678-16684, 2021.
R
M. Kumar Bisai, Sharma, V., Gonnade, R. G., and Sen, S. S., “Reactivities of silaimines with boranes: from cooperative B-H bond activation to donor stabilized silyl cation”, Organometallics, vol. 40, no. 13, pp. 2133-2138, 2021.
M. Kumar Bisai, Gour, K., Das, T., Vanka, K., and Sen, S. S., “Readily available lithium compounds as catalysts for the hydroboration of carbodiimides and esters”, Journal of Organometallic Chemistry, vol. 949, p. 121924, 2021.
S
G. Kundu, De, S., Tothadi, S., Das, A., Koley, D., and Sen, S. S., “Saturated N-heterocyclic carbene based thiele's hydrocarbon with a tetrafluorophenylene linker”, Chemistry-A European Journal, 2019.
S. S. Sen and Roesky, H. W., “Silanetriols and aluminosilicates”, in Efficient methods for preparing silicon compounds, Netherland: Academic Press, Elsevier, 2016, pp. 221-231.
S. S. Sen and Roesky, H. W., “Silicon-fluorine chemistry: from the preparation of SiF2 to C-F bond activation using silylenes and its heavier congeners”, Chemical Communications, vol. 54, no. 40, pp. 5046-5057, 2018.
V. S. V. S. N. Swamy, K. Raj, V., Vanka, K., Sen, S. S., and Roesky, H. W., “Silylene induced cooperative B-H bond activation and unprecedented aldehyde C-H bond splitting with amidinate ring expansion”, Chemical Communications, vol. 55, no. 24, pp. 3536-3539, 2019.
K. Gour, Kundu, G., Dash, S. Ranjan, Vanka, K., Tothadi, S., and Sen, S. S., “Six-membered NHC stabilized monomeric zinc complexes”, European Journal of Inorganic Chemistry, vol. 26, no. 21, p. e202300167, 2023.
G. Kundu, Balayan, K., Tothadi, S., and Sen, S. S., “Six-membered saturated NHC-stabilized borenium cations: isolation of a cationic analogue of borinic acid”, Inorganic Chemistry, vol. 61, no. 33, pp. 12991-12997, 2022.
S. S. Sen, “Stable silanone with a three-coordinate silicon atom: a century-long wait is over”, Angewandte Chemie-International Edition, vol. 53, no. 34, pp. 8820-8822, 2014.
H. Braunschweig, Celik, M. Ali, Dewhurst, R. D., Heid, M., Hupp, F., and Sen, S. S., “Stepwise isolation of low-valent, low-coordinate Sn and Pb mono- and dications in the coordination sphere of platinum”, Chemical Science, vol. 6, no. 1, pp. 425-435, 2015.
G. Kundu, Pahar, S., Tothadi, S., and Sen, S. S., “Stepwise nucleophilic substitution to access saturated N-heterocyclic carbene haloboranes with boron-methyl bonds”, Organometallics, vol. 39, pp. 4696-4703, 2020.
N. Parvin, Dasgupta, R., Pal, S., Sen, S. S., and Khan, S., “Strikingly diverse reactivity of structurally identical silylene and stannylene”, Dalton Transactions, vol. 46, no. 20, pp. 6528-6532, 2017.
G. Kundu, Ajithkumar, V. S., K. Raj, V., Vanka, K., Tothadi, S., and Sen, S. S., “Substitution at sp(3) boron of a six-membered NHC center dot BH3: convenient access to a dihydroxyborenium cation”, Chemical Communications, vol. 58, no. 23, pp. 3783-3786, 2022.
R. Dixit, Bisai, M. Kumar, Yadav, S., Yadav, V., Sen, S. S., and Vanka, K., “Substrate, catalyst, and solvent: the triune nature of multitasking reagents in hydroboration and cyanosilylation”, Organometallics, vol. 40, no. 8, pp. 1104-1112, 2021.
M. Kumar Bisai, Swamy, V. S. V. S. N., Das, T., Vanka, K., Gonnade, R. G., and Sen, S. S., “ Synthesis and reactivity of a hypersilylsilylene ”, Inorganic chemistry, vol. 58, no. 16, pp. 10536-10542, 2019.
V. S. Ajithkumar, Ghanwat, P. B., K. Raj, V., Vanka, K., Gonnade, R. G., and Sen, S. S., “Synthesis of Si(IV)- and Ge(II)-substituted amines, hydrazone, and hydrazine from hypersilyl germylene”, Organometallics, vol. 42, no. 20, pp. 2983-2990, 2023.
S. S. Sen and Roesky, H. W., “Synthesis of silicon(II) compounds and their reactions”, in Efficient methods for preparing silicon compounds, Netherland: Academic Press, Elsevier, 2016, pp. 233-242.
T
R. Kumar, Yadav, S., Gour, K., Sangtani, E., Dash, S. Ranjan, Raja, A., Vanka, K., Gonnade, R. G., and Sen, S. S., “Tale of biphenyl and terphenyl substituents for structurally diverse ketiminato magnesium, calcium and germanium complexes”, Chemistry-An Asian Journal, vol. 15, no. 6, pp. 820-827, 2020.
G. Kundu, Amrutha, P. R., K. Raj, V., Tothadi, S., Vanka, K., and Sen, S. S., “Taming the parent oxoborane”, Chemical Science, vol. 14, no. 22, pp. 5894-5898, 2023.
M. Bisai, Pahar, S., Das, T., and Sen, S. S., “Transition metal free catalytic hydroboration of aldehydes and aldimines by amidinato silane”, Dalton Transactions, vol. 46, pp. 2420 - 2424, 2017.
B. Raghavendra, Bakthavachalam, K., Das, T., Roisnel, T., Sen, S. S., Vanka, K., and Ghosh, S., “Transmetallation vs adduct: diverse reactivity of N,O-ketiminato germylene with [Cp*MCl2](2) (M = Rh or Ir; Cp* = eta(5)-C5Me5) and MCl5 (M = Nb and Ta)”, Journal of Organometallic Chemistry, vol. 911, p. 121142, 2020.
S. Pahar, Sharma, V., Mahata, B., George, C. P., Sharma, H., Vanka, K., and Sen, S. S., “Tridentate NacNac stabilized tin and nickel complexes: access to a monomeric nickel hydride and its catalytic application”, Inorganic Chemistry, vol. 61, no. 43, pp. 17370-17377, 2022.
U
S. Yadav, Sangtani, E., Dhawan, D., Gonnade, R. G., Ghosh, D., and Sen, S. S., “Unprecedented solvent induced inter-conversion between monomeric and dimeric silylene-zinc iodide adducts”, Dalton Transaction , vol. 46, no. 34, 2017.
M. Kumar Bisai, Das, T., Vanka, K., Gonnade, R. G., and Sen, S. S., “Unsymmetrical sp(2)-sp(3) disilenes”, Angewandte Chemie-International Edition, vol. 60, no. 38, pp. 20706-20710, 2021.
V
G. Kundu, Dixit, R., Tothadi, S., Vanka, K., and Sen, S. S., “Versatile chemistry of six-membered NHC with boranes: bromination at sp(3) borane, activation of the B-H bond of HBpin, and ring expansion of NHC”, Dalton Transactions, vol. 51, no. 38, pp. 14452-14457, 2022.
W
R. Kumar, Sharma, V., Jain, S., Sharma, H., Vanka, K., and Sen, S. S., “Well-defined calcium compound catalyzes trimerization of arylisocyanates into 1,3,5-triarylisocyanurates”, ChemCatChem, vol. 14, no. 11, p. e202101788, 2022.
Z
M. Kumar Bisai, Ajithkumar, V. S., K. Raj, V., Vanka, K., Gonnade, R. G., and Sen, S. S., “Zwitterionic disilanylium from an unsymmetrical disilene”, Chemical Communications, vol. 59, no. 12, pp. 1669-1672, 2023.