Access to diverse germylenes and a six-membered dialane with a flexible beta-diketiminate
| Title | Access to diverse germylenes and a six-membered dialane with a flexible beta-diketiminate |
| Publication Type | Journal Article |
| Year of Publication | 2020 |
| Authors | Pahar, S, Swamy, VSVSN, Das, T, Gonnade, RG, Vanka, K, Sen, SS |
| Journal | Chemical Communications |
| Volume | 56 |
| Issue | 79 |
| Pagination | 11871-11874 |
| Date Published | OCT |
| Type of Article | Article |
| ISSN | 1359-7345 |
| Abstract | A nacnac-based tridentate ligand containing a picolyl group (L) was employed to isolate chlorogermylene (1). The reaction of1with another equivalent of GeCl2 center dot dioxane surprisingly gave pyridylpyrrolide-based chlorogermylene (2)viaC-N bond cleavage and C-C coupling, while with AlCl3, it afforded a transmetalated product,4. The reaction of L with AlH3 center dot NMe2Et led to an unusual cyclohexane type six-membered dialane heterocycle (5). |
| DOI | 10.1039/d0cc05202g |
| Type of Journal (Indian or Foreign) | Foreign |
| Impact Factor (IF) | 5.996 |
Divison category:
Catalysis and Inorganic Chemistry
Physical and Materials Chemistry