Facile activation of Si-H bond by an electrophilic carbene
| Title | Facile activation of Si-H bond by an electrophilic carbene |
| Publication Type | Journal Article |
| Year of Publication | 2018 |
| Authors | Swamy, VSVSN, Kundu, G, Sen, SS |
| Journal | Indian Chemical Society |
| Volume | 95 |
| Issue | 7 |
| Pagination | 789-793 |
| Date Published | JUL |
| Type of Article | Article |
| ISSN | 0019-4522 |
| Abstract | Herein, we have explored the chemistry of 1,3-bis(2,6-di-isopropylphenyl)-5,5-dimethy1-4,6-diketopyrimidinyl-2-ylidene (1) with various silanes under mild conditions. The oxidative addition of Si-H bond of phenylsilane with DAC 1 affords the compound 2, which is unambiguously characterized by muitinuclear NMR spectroscopy, elemental analysis, and X-ray single crystal diffraction studies. Interestingly, DAC 1 activates silicon hydride bond of chlorosilanes at room temperature and results in the corresponding silylation products. |
| Type of Journal (Indian or Foreign) | Indian |
| Impact Factor (IF) | 0.204 |
Divison category:
Catalysis and Inorganic Chemistry
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