Lithium compound catalyzed deoxygenative hydroboration of primary, secondary and tertiary amides

TitleLithium compound catalyzed deoxygenative hydroboration of primary, secondary and tertiary amides
Publication TypeJournal Article
Year of Publication2021
AuthorsBisai, MKumar, Gour, K, Das, T, Vanka, K, Sen, SS
JournalDalton Transactions
Volume50
Issue7
Pagination2354-2358
Date PublishedFEB
Type of ArticleArticle
ISSN1477-9226
Abstract

A selective and efficient route for the deoxygenative reduction of primary to tertiary amides to corresponding amines has been achieved with pinacolborane (HBpin) using simple and readily accessible 2,6-di-tert-butyl phenolate lithium center dot THF (1a) as a catalyst. Both experimental and DFT studies provide mechanistic insight.

DOI10.1039/d1dt00364j
Type of Journal (Indian or Foreign)

Foreign

Impact Factor (IF)4.390
Divison category: 
Catalysis and Inorganic Chemistry
Physical and Materials Chemistry

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