Silylene induced cooperative B-H bond activation and unprecedented aldehyde C-H bond splitting with amidinate ring expansion
| Title | Silylene induced cooperative B-H bond activation and unprecedented aldehyde C-H bond splitting with amidinate ring expansion |
| Publication Type | Journal Article |
| Year of Publication | 2019 |
| Authors | Swamy, VSVSN, K. Raj, V, Vanka, K, Sen, SS, Roesky, HW |
| Journal | Chemical Communications |
| Volume | 55 |
| Issue | 24 |
| Pagination | 3536-3539 |
| Date Published | MAR |
| Type of Article | Article |
| ISSN | 1359-7345 |
| Abstract | The addition of HBpin to PhC(NtBu)(2)SiN(SiMe3)(2) (1) results in the cleavage of the B-H bond in a cooperative fashion across the Si and amidinate-C sites. The reaction of 1 with benzaldehyde led to C-H bond activation with amidinate ring expansion leading to a five-membered heterocycle. In case of 4-fluorobenzaldehyde, a C-C bond coupling takes place leading to a dioxasilolane derivative as the major product. |
| DOI | 10.1039/c9cc00296k |
| Type of Journal (Indian or Foreign) | Foreign |
| Impact Factor (IF) | 6.164 |
Divison category:
Catalysis and Inorganic Chemistry
Physical and Materials Chemistry