C(sp(3))-F, C(sp(2))-F and C(sp(3))-H bond activation at silicon(II) centers
| Title | C(sp(3))-F, C(sp(2))-F and C(sp(3))-H bond activation at silicon(II) centers |
| Publication Type | Journal Article |
| Year of Publication | 2017 |
| Authors | Swamy, VSVSN, Parvin, N, K. Raj, V, Sen, SS |
| Journal | Chemical Communication |
| Volume | 53 |
| Start Page | 9850-9853 |
| Issue | 71 |
| Date Published | SEP |
| ISSN | 1359-7345 |
| Keywords | Boron triple bond, C-F Bond, Fluorinated Building-Block, H Activation, Ketones, N-heterocyclic carbenes, Oxodative Addition, Perfluorinated Arenes, Selective Activation, Transition-Metal Centers |
| Abstract | Silylene [PhC(NtBu)(2)SiN(SiMe3)(2)] (1) cleaves the C(sp(3))-H and C-F bonds of acetophenone and 1,1,1-trifluoroacetophenone, respectively, under mild conditions. The reaction is initiated via a nucleophilic attack from the oxygen to the silicon atom followed by C-F/H bond cleavage. The scope of C-F bond activation has further been extended with C6F6 and C6F5CF3. |
| DOI | 10.1039/c7cc05145j |
| Type of Journal (Indian or Foreign) | Foreign |
| Impact Factor (IF) | 6.567 |
Divison category:
Catalysis and Inorganic Chemistry