Carbohydrate based total synthesis of xestodecalactone B and C: revision of the absolute configuration

TitleCarbohydrate based total synthesis of xestodecalactone B and C: revision of the absolute configuration
Publication TypeJournal Article
Year of Publication2012
AuthorsPal, R, Rahaman, H, Gurjar, MK
JournalCurrent Organic Chemistry
Volume16
Issue9
Pagination1159-1168
Date PublishedMAY
ISSN1385-2728
KeywordsChiral pool, Hydroboration, Intramolecular acylation, Pinnick oxidation, Revision of absolute configuration, Xestodecalactone B and C
Abstract

A convergent chiral pool approach for the total synthesis of xestodecalactones B and C was demonstrated in which intramolecular acylation reaction constituted the key step. Synthetic and spectroscopic studies reported herein, suggested that the previously assigned structures of xestodecalactone B and C be interchanged.

Type of Journal (Indian or Foreign)Foreign
Impact Factor (IF)3.039
Divison category: 
Organic Chemistry