01266nas a2200241 4500008004100000022001400041245010700055210006900162260011100231300001400342490000700356520033200363653001600695653001800711653002900729653002200758653003900780653002900819100001400848700002100862700002300883856011800906 2012 eng d a1385-272800aCarbohydrate based total synthesis of xestodecalactone B and C: revision of the absolute configuration0 aCarbohydrate based total synthesis of xestodecalactone B and C r aEXECUTIVE STE Y26, PO BOX 7917, SAIF ZONE, 1200 BR SHARJAH, U ARAB EMIRATESbBENTHAM SCIENCE PUBL LTDcMAY a1159-11680 v163 a
A convergent chiral pool approach for the total synthesis of xestodecalactones B and C was demonstrated in which intramolecular acylation reaction constituted the key step. Synthetic and spectroscopic studies reported herein, suggested that the previously assigned structures of xestodecalactone B and C be interchanged.
10aChiral pool10aHydroboration10aIntramolecular acylation10aPinnick oxidation10aRevision of absolute configuration10aXestodecalactone B and C1 aPal, Rita1 aRahaman, Hasibur1 aGurjar, Mukund, K. uhttp://library.ncl.res.in/content/carbohydrate-based-total-synthesis-xestodecalactone-b-and-c-revision-absolute-0