TY - JOUR T1 - Carbohydrate based total synthesis of xestodecalactone B and C: revision of the absolute configuration JF - Current Organic Chemistry Y1 - 2012 A1 - Pal, Rita A1 - Rahaman, Hasibur A1 - Gurjar, Mukund K. KW - Chiral pool KW - Hydroboration KW - Intramolecular acylation KW - Pinnick oxidation KW - Revision of absolute configuration KW - Xestodecalactone B and C AB -

A convergent chiral pool approach for the total synthesis of xestodecalactones B and C was demonstrated in which intramolecular acylation reaction constituted the key step. Synthetic and spectroscopic studies reported herein, suggested that the previously assigned structures of xestodecalactone B and C be interchanged.

PB - BENTHAM SCIENCE PUBL LTD CY - EXECUTIVE STE Y26, PO BOX 7917, SAIF ZONE, 1200 BR SHARJAH, U ARAB EMIRATES VL - 16 IS - 9 U3 - Foreign U4 - 3.039 ER -