Bimetallic Ni-Pd synergism-mixed metal catalysis of the mizoroki-heck reaction and the suzuki-miyaura coupling of aryl bromides
| Title | Bimetallic Ni-Pd synergism-mixed metal catalysis of the mizoroki-heck reaction and the suzuki-miyaura coupling of aryl bromides |
| Publication Type | Journal Article |
| Year of Publication | 2021 |
| Authors | Kashid, AA, Patil, DJ, Mali, RD, Patil, VP, Neethu, TV, Meroliya, HK, Waghmode, SA, Iyer, S |
| Journal | Catalysis Letters |
| Volume | 151 |
| Issue | 2 |
| Pagination | 353-358 |
| Date Published | FEB |
| Type of Article | Article |
| ISSN | 1011-372X |
| Keywords | Bimetallic catalysis, Mizoroki-Heck, Nickel complexes, Pd(OAc)2, Suzuki coupling |
| Abstract | A combination of Pd and Ni complexes activated aryl bromides for the thermal Mizoroki-Heck reaction and Suzuki coupling giving high yields in short reaction times. A thermal redox mechanism probably occurs whereby Ni complex transfers electron and reduces the Pd (II) to Pd (0) which then takes the reactants through the standard protocol of oxidative-addition, migratory insertion and reductive elimination, typical for the Mizoroki-Heck reaction and the Suzuki coupling. [GRAPHICS] . |
| DOI | 10.1007/s10562-020-03330-9, Early Access Date = AUG 2020 |
| Type of Journal (Indian or Foreign) | Foreign |
| Impact Factor (IF) | 3.186 |
Divison category:
Organic Chemistry