TY - JOUR T1 - Bimetallic Ni-Pd synergism-mixed metal catalysis of the mizoroki-heck reaction and the suzuki-miyaura coupling of aryl bromides JF - Catalysis Letters Y1 - 2021 A1 - Kashid, Abhijit A. A1 - Patil, Dharmaraj J. A1 - Mali, Ramling D. A1 - Patil, Vijay P. A1 - Neethu, T. V. A1 - Meroliya, Heena K. A1 - Waghmode, Shobha A. A1 - Iyer, Suresh KW - Bimetallic catalysis KW - Mizoroki-Heck KW - Nickel complexes KW - Pd(OAc)2 KW - Suzuki coupling AB -

A combination of Pd and Ni complexes activated aryl bromides for the thermal Mizoroki-Heck reaction and Suzuki coupling giving high yields in short reaction times. A thermal redox mechanism probably occurs whereby Ni complex transfers electron and reduces the Pd (II) to Pd (0) which then takes the reactants through the standard protocol of oxidative-addition, migratory insertion and reductive elimination, typical for the Mizoroki-Heck reaction and the Suzuki coupling. [GRAPHICS] .

VL - 151 IS - 2 U3 -

Foreign

U4 - 3.186 ER -