Amino acid amide based ionic liquid as an efficient organo-catalyst for solvent-free knoevenagel condensation at room temperature
Title | Amino acid amide based ionic liquid as an efficient organo-catalyst for solvent-free knoevenagel condensation at room temperature |
Publication Type | Journal Article |
Year of Publication | 2019 |
Authors | Burate, PA, Javle, BR, Desale, PH, Kinage, AK |
Journal | Catalysis Letters |
Volume | 149 |
Issue | 9 |
Pagination | 2368-2375 |
Date Published | SEP |
Type of Article | Article |
ISSN | 1011-372X |
Keywords | Acrylonitrile, Amino acid amide, Cyanoacrylate, Ionic liquid, Knoevenagel condensation, Solvent-free |
Abstract | Ionic liquids of amino acid amide were synthesized and used as an efficient catalyst for solvent-free Knoevenagel condensation. Synthesized ionic liquids are an environmentally benign, inexpensive, metal free and plays the dual role of solvent as well as an efficient catalyst for Knoevenagel condensation. A wide range of aliphatic, aromatic and heteroaromatic aldehydes easily undergo condensation with malononitrile and ethyl cyanoacetate. The reaction proceeds at room temperature without using any organic solvent and is very fast with good to excellent yield. Additionally, the catalyst is easily separable and recyclable without loss of activity. [GRAPHICS] . |
DOI | 10.1007/s10562-019-02840-5 |
Type of Journal (Indian or Foreign) | Foreign |
Impact Factor (IF) | 2.372 |
Divison category:
Chemical Engineering & Process Development
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