Multiple H2 occupancy of cages of clathrate hydrate under mild condition
| Title | Multiple H2 occupancy of cages of clathrate hydrate under mild condition |
| Publication Type | Journal Article |
| Year of Publication | 2012 |
| Authors | Lu, H, Wang, J, Liu, C, Ratcliffe, CI, Becker, U, Kumar, R, Ripmeester, JA |
| Journal | Journal of the American Chemical Society |
| Volume | 134 |
| Issue | 22 |
| Pagination | 9160 - 9162 |
| Date Published | MAY |
| Abstract | Experiments were carried out by reacting H(2) gas with N(2) hydrate at a temperature of 243 K and a pressure of 15 MPa. The characterizations of the reaction products indicated that multiple H(2) molecules can be loaded into both large and small cages of structure II clathrate hydrates. The realization of multiple H(2) occupancy of hydrate cages under moderate conditions not only brings new insights into hydrogen clathrates but also refreshes the perspective of clathrate hydrates as hydrogen storage media. |
| DOI | 10.1021/ja303222u |
| Type of Journal (Indian or Foreign) | Foreign |
| Impact Factor (IF) | 13.038 |
Divison category:
Chemical Engineering & Process Development