TY - JOUR T1 - Multiple H2 occupancy of cages of clathrate hydrate under mild condition JF - Journal of the American Chemical Society Y1 - 2012 A1 - Lu, Hailong A1 - Wang, Jianwei A1 - Liu, Changling A1 - Ratcliffe, Christopher I. A1 - Becker, Udo A1 - Kumar, Rajnish A1 - Ripmeester, John A. AB - Experiments were carried out by reacting H(2) gas with N(2) hydrate at a temperature of 243 K and a pressure of 15 MPa. The characterizations of the reaction products indicated that multiple H(2) molecules can be loaded into both large and small cages of structure II clathrate hydrates. The realization of multiple H(2) occupancy of hydrate cages under moderate conditions not only brings new insights into hydrogen clathrates but also refreshes the perspective of clathrate hydrates as hydrogen storage media. VL - 134 IS - 22 U3 - Foreign U4 - 13.038 ER -