Hypervalent-iodine-mediated oxidation followed by the acetoxylation/tosylation of alpha-substituted benzylamines to obtain alpha-acyloxy/tosyloxy ketones
| Title | Hypervalent-iodine-mediated oxidation followed by the acetoxylation/tosylation of alpha-substituted benzylamines to obtain alpha-acyloxy/tosyloxy ketones |
| Publication Type | Journal Article |
| Year of Publication | 2022 |
| Authors | Rupanawar, BD, Mane, KD, Suryavanshi, G |
| Journal | New Journal of Chemistry |
| Volume | 46 |
| Issue | 35 |
| Pagination | 16832-16839 |
| Date Published | SEP |
| Type of Article | Article |
| ISSN | 1144-0546 |
| Abstract | An efficient and metal-free method has been developed for the sequential oxidation of alpha-alkylbenzylamines followed by acetoxylation or tosylation for the synthesis of alpha-acyloxy/tosyloxy ketones using hypervalent iodine(iii). The employment of a simple starting material, broad substrate scope and operational simplicity are the key features of this protocol. |
| DOI | 10.1039/d2nj02271k |
| Type of Journal (Indian or Foreign) | Foreign |
| Impact Factor (IF) | 3.925 |
Divison category:
Chemical Engineering & Process Development
Database:
Web of Science (WoS)
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