High hydroxide conductivity in a chemically stable crystalline metal-organic framework containing a water-hydroxide supramolecular chain

TitleHigh hydroxide conductivity in a chemically stable crystalline metal-organic framework containing a water-hydroxide supramolecular chain
Publication TypeJournal Article
Year of Publication2016
AuthorsNagarkar, SS, Anothumakkool, B, Desai, AV, Shirolkar, MM, Kurungot, S, Ghosh, SK
JournalChemical Communications
Volume52
Issue54
Pagination8459-8462
Date PublishedJUN
ISSN1359-7345
Abstract

A chemically stable cationic MOF encapsulating an in situ formed water-hydroxide supramolecular anionic chain is realized for high hydroxide (OH-) ion conductivity in the solid-state (Type A). High OH- ion conductivity and low activation energy of the MOF demonstrate the advantage of the in situ incorporation of OH- ions to achieve efficient OH- ion conduction in the solid-state.

DOI10.1039/c6cc04436k
Type of Journal (Indian or Foreign)

Foreign

Impact Factor (IF)6.567
Divison category: 
Physical and Materials Chemistry