Eutectic mixture-directed kinetics of Diels-Alder reaction
Title | Eutectic mixture-directed kinetics of Diels-Alder reaction |
Publication Type | Journal Article |
Year of Publication | 2011 |
Authors | Nagare, AS, Kumar, A |
Journal | Indian Journal of Chemistry Section A-Inorganic Bio-Inorganic Physical Theoretical & Analytical Chemistry |
Volume | 50 |
Issue | 6 |
Pagination | 788-792 |
Date Published | JUN |
ISSN | 0376-4710 |
Keywords | carbohydrates, Cycloaddition, Diels-Alder reaction, Dimethylurea, kinetics, Reaction rates, solvent effects, Urea, viscosity |
Abstract | In the search for environmentally benign solvent media, a new class of solvents composed of mixtures of carbohydrates with urea or methylated urea has been noted to be effective in enhancing the reaction rates of a bimolecular organic reaction like the Diels-Alder reaction of cyclopentadiene with methyl acrylate. The viscosity of these media appears to be an important parameter in controlling the second order kinetics. |
Type of Journal (Indian or Foreign) | Indian |
Impact Factor (IF) | 0.76 |
Divison category:
Physical and Materials Chemistry