Eutectic mixture-directed kinetics of Diels-Alder reaction

TitleEutectic mixture-directed kinetics of Diels-Alder reaction
Publication TypeJournal Article
Year of Publication2011
AuthorsNagare, AS, Kumar, A
JournalIndian Journal of Chemistry Section A-Inorganic Bio-Inorganic Physical Theoretical & Analytical Chemistry
Volume50
Issue6
Pagination788-792
Date PublishedJUN
ISSN0376-4710
Keywordscarbohydrates, Cycloaddition, Diels-Alder reaction, Dimethylurea, kinetics, Reaction rates, solvent effects, Urea, viscosity
Abstract

In the search for environmentally benign solvent media, a new class of solvents composed of mixtures of carbohydrates with urea or methylated urea has been noted to be effective in enhancing the reaction rates of a bimolecular organic reaction like the Diels-Alder reaction of cyclopentadiene with methyl acrylate. The viscosity of these media appears to be an important parameter in controlling the second order kinetics.

Type of Journal (Indian or Foreign)

Indian

Impact Factor (IF)0.76
Divison category: 
Physical and Materials Chemistry