TY - JOUR T1 - Eutectic mixture-directed kinetics of Diels-Alder reaction JF - Indian Journal of Chemistry Section A-Inorganic Bio-Inorganic Physical Theoretical & Analytical Chemistry Y1 - 2011 A1 - Nagare, Amit S. A1 - Kumar, Anil KW - carbohydrates KW - Cycloaddition KW - Diels-Alder reaction KW - Dimethylurea KW - kinetics KW - Reaction rates KW - solvent effects KW - Urea KW - viscosity AB -

In the search for environmentally benign solvent media, a new class of solvents composed of mixtures of carbohydrates with urea or methylated urea has been noted to be effective in enhancing the reaction rates of a bimolecular organic reaction like the Diels-Alder reaction of cyclopentadiene with methyl acrylate. The viscosity of these media appears to be an important parameter in controlling the second order kinetics.

PB - NATL INST SCIENCE COMMUNICATION-NISCAIR CY - DR K S KRISHNAN MARG, PUSA CAMPUS, NEW DELHI 110 012, INDIA VL - 50 IS - 6 U3 -

Indian

U4 - 0.76 ER -