Rational design of reduced graphene oxide/TiO2/gold nanorod nanocomposite for complete degradation of polystyrene microplastics in wastewater

TitleRational design of reduced graphene oxide/TiO2/gold nanorod nanocomposite for complete degradation of polystyrene microplastics in wastewater
Publication TypeJournal Article
Year of Publication2025
AuthorsUshaVipinachandran, V, Naveenkumar, K, Haroon, KHussain Ba, Ashokan, I, Sinha, A, Maity, P, Bhunia, SKumar
JournalAdvanced Sustainable Systems
Volume9
Issue8
Date PublishedAUG
Type of ArticleArticle
ISSN2366-7486
Keywordschemical degradation, Photocatalysis, plasmonic hot electron, polystyrene microplastics, Reduced graphene oxide
Abstract

Our planet is being devoured by plastic consumption every day. Water, soil, and air are deliberately polluted by the ingredients of these nondegradable plastics. Extensive usage of plastic has serious consequences in the environment, wildlife, and human health. A comprehensive approach to eradicate plastics from the planet is therefore imperative. Herein, a ternary nanocomposite subsumed of reduced graphene oxide (rGO), titanium dioxide (TiO2), and gold nanorods (AuNRs) is synthesized and effectively deployed to remove plastics from water as well as degradation of polymer film by both chemically and photocatalytically. The hydrothermally prepared nanocomposite completely removes polystyrene molecules from water, and 1.2 mg of plastic degradation is observed during the photolysis. Conversely, chemical degradation pathway induces the weight loss of 10.7 mg. Both Plasmon-induced interfacial charge transfer transition (PICTT) and Plasmon-induced hot electron transfer (PHET) assist the formation of reactive oxygen species (ROS) that collectively degrades the polymer strands. The spectrochemical and microscopic studies validate the degradation studies with cautious conclusions.

DOI10.1002/adsu.202500096
Type of Journal (Indian or Foreign)

Foreign

Impact Factor (IF)

6.1

Divison category: 
Organic Chemistry
Database: 
Web of Science (WoS)

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