Silylene-copper(i) catalysis: regioselective protoboration of terminal alkynes
| Title | Silylene-copper(i) catalysis: regioselective protoboration of terminal alkynes |
| Publication Type | Journal Article |
| Year of Publication | 2025 |
| Authors | Kaulage, SH, Shah, BKumar, Panday, R, Sharma, H, Vanka, K, Khan, S |
| Journal | Chemical Communications |
| Volume | 61 |
| Issue | 99 |
| Pagination | 19652-19655 |
| Date Published | DEC |
| Type of Article | Article |
| ISSN | 1359-7345 |
| Abstract | Herein, we report an efficient regioselective protoboration of the terminal alkynes catalyzed by newly synthesized silylene-copper(i)-aryl complexes. This method offers a broad substrate scope, good functional-group compatibility, and a gram-scale synthetic ability. The insight into the mechanistic cycle is also provided with the support of experimental and theoretical studies. |
| DOI | 10.1039/d5cc06125c |
| Type of Journal (Indian or Foreign) | Foreign |
| Impact Factor (IF) | 4.2 |
Divison category:
Physical and Materials Chemistry
Database:
Web of Science (WoS)
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