Synthesis of 5-hydroxymethylfurfural from glucose using a tert-butoxyapatite catalyst
| Title | Synthesis of 5-hydroxymethylfurfural from glucose using a tert-butoxyapatite catalyst |
| Publication Type | Journal Article |
| Year of Publication | 2025 |
| Authors | Kulkarni, HS, Kamble, PA, Vinod, CP, Rathod, VK, Kantam, MLakshmi |
| Journal | DALTON TRANSACTIONS |
| Volume | 54 |
| Issue | 36 |
| Pagination | 13574-13587 |
| Date Published | SEP |
| Type of Article | Article |
| ISSN | 1477-9226 |
| Abstract | In this study, 5-hydroxymethylfurfural (5-HMF) was obtained from glucose using tert-butoxyapatite, a heterogeneous catalyst. The tert-butoxyapatite catalyst was prepared and characterized by several techniques, such as XRD, SEM, TEM, EDS, elemental mapping HR-TEM, N2-adsorption/desorption, XPS, and FT-IR. Several parameters were studied, such as temperature, catalyst loading, and glucose concentration. The tert-butoxyapatite catalyst having both acidic and basic sites gave a maximum glucose conversion of 87% with a 48% yield of HMF at 160 degrees C using 20 wt% catalyst in 12 h. Reusability studies of the catalyst are also presented. |
| DOI | 10.1039/d5dt01450f |
| Type of Journal (Indian or Foreign) | Foreign |
| Impact Factor (IF) | 3.3 |
Divison category:
Catalysis and Inorganic Chemistry
Database:
Web of Science (WoS)
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