Synthesis of diamido N-heterocyclic imines (DAC = NH) via staudinger or reductive N-N bond cleavage approach
| Title | Synthesis of diamido N-heterocyclic imines (DAC = NH) via staudinger or reductive N-N bond cleavage approach |
| Publication Type | Journal Article |
| Year of Publication | 2025 |
| Authors | Balayan, K, Sharma, H, Vanka, K, Gonnade, RG, Sen, SS |
| Journal | Organometallics |
| Volume | 44 |
| Issue | 11 |
| Pagination | 1129-1133 |
| Date Published | MAY |
| Type of Article | Article |
| ISSN | 0276-7333 |
| Abstract | This report communicates the first examples of N-heterocyclic imines based on electrophilic diamido carbenes (DACs). While 2 is prepared by classical Staudinger synthesis, 4 is obtained via an unusual reductive N-N bond cleavage of an azine by HCl. The exocyclic C=N bond lengths in 2 and 4 are substantially shorter than those based on N-heterocyclic carbenes and cyclic (alkyl)(amino)carbene reflecting the electrophilic character of DACs. |
| DOI | 10.1021/acs.organomet.5c00120 |
| Type of Journal (Indian or Foreign) | Foreign |
| Impact Factor (IF) | 2.7 |
Divison category:
Catalysis and Inorganic Chemistry
Physical and Materials Chemistry
Database:
Web of Science (WoS)
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