Activation of carbon disulfide by a hypersilyl germylene
| Title | Activation of carbon disulfide by a hypersilyl germylene |
| Publication Type | Journal Article |
| Year of Publication | 2024 |
| Authors | Ajithkumar, VS, Khilari, N, Ghanwat, PB, Venugopal, G, Koley, D, Sen, SS |
| Journal | Dalton Transactions |
| Volume | 53 |
| Issue | 26 |
| Date Published | JUL |
| Type of Article | Article |
| ISSN | 1477-9226 |
| Abstract | In this work, the insertion of CS2 into the Ge-Si bond of PhC(NtBu)2Ge-Si(SiMe3)3 (1) has been investigated, resulting in the formation of PhC(NtBu)2Ge-C( 00000000 00000000 00000000 00000000 11111111 00000000 11111111 00000000 00000000 00000000 S)-S-Si(SiMe3)3 (2). Interestingly, the addition of NHC to 2 allows the release of NHCCS2 with concomitant regeneration of 1. Addition of another equivalent of 1 or an analogous hypersilyl silylene, [PhC(NtBu)2Si-Si(SiMe3)3], to 2 led to the formation of compounds with a GeS (3) or a SiS (4) bond. In this work, the insertion of CS2 into the Ge-Si bond of PhC(NtBu)2Ge-Si(SiMe3)3 (1) has been investigated, resulting in the formation of PhC(NtBu)2Ge-C(S)-S-Si(SiMe3)3 (2). |
| DOI | 10.1039/d4dt01573h |
| Type of Journal (Indian or Foreign) | Foreign |
| Impact Factor (IF) | 4 |
Divison category:
Catalysis and Inorganic Chemistry
Organic Chemistry
Database:
Web of Science (WoS)
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