Zwitterionic disilanylium from an unsymmetrical disilene
| Title | Zwitterionic disilanylium from an unsymmetrical disilene |
| Publication Type | Journal Article |
| Year of Publication | 2023 |
| Authors | Bisai, MKumar, Ajithkumar, VS, K. Raj, V, Vanka, K, Gonnade, RG, Sen, SS |
| Journal | Chemical Communications |
| Volume | 59 |
| Issue | 12 |
| Pagination | 1669-1672 |
| Date Published | FEB |
| Type of Article | Article |
| ISSN | 1359-7345 |
| Abstract | The reaction of PhC(NtBu)2SiSi(SiMe3)(3) (1) with Me3SiCH(2)Cl afforded an unsymmetrical sp(2)-sp(3) disilene, 2, with concomitant elimination of Me3SiCl. The analogous reaction with PhC(NtBu)2SiCl resulted in the oxidative addition of the C-Cl bond at the Si(II) atom (3). The reactions of 2 with sulfur and selenium led to compounds with Si=E (E=S (4) and Se (5)) double bonds. Tellurium reacted differently with 2 and furnished a zwitterionic compound, 6. |
| DOI | 10.1039/d2cc06954g |
| Type of Journal (Indian or Foreign) | Foreign |
| Impact Factor (IF) | 4.9 |
Divison category:
Catalysis and Inorganic Chemistry
Physical and Materials Chemistry
Database:
Web of Science (WoS)