On the competition between six-membered and five-membered NHC towards alane centered ring expansion
| Title | On the competition between six-membered and five-membered NHC towards alane centered ring expansion |
| Publication Type | Journal Article |
| Year of Publication | 2023 |
| Authors | Balayan, K, Sharma, H, Vanka, K, Ravindranathan, S, Gonnade, RG, Sen, SS |
| Journal | Chemical Communications |
| Volume | 59 |
| Issue | 55 |
| Pagination | 8540-8543 |
| Date Published | JUL |
| Type of Article | Article |
| ISSN | 1359-7345 |
| Abstract | The combination of 6-SIDipp center dot AlH3 (1) and 5-IDipp resulted in the ring expansion of 6-NHC, while the five-membered NHC remained unchanged, which was subsequently explained by DFT studies. Besides, the substitution chemistry of 1 was also studied with TMSOTf and I-2, which gave rise to the substitution of a hydride by triflate or iodide ligands. |
| DOI | 10.1039/d3cc02063k |
| Type of Journal (Indian or Foreign) | Foreign |
| Impact Factor (IF) | 4.9 |
Divison category:
Catalysis and Inorganic Chemistry
Central NMR Facility
Physical and Materials Chemistry
Database:
Web of Science (WoS)