On the competition between six-membered and five-membered NHC towards alane centered ring expansion
Title | On the competition between six-membered and five-membered NHC towards alane centered ring expansion |
Publication Type | Journal Article |
Year of Publication | 2023 |
Authors | Balayan, K, Sharma, H, Vanka, K, Ravindranathan, S, Gonnade, RG, Sen, SS |
Journal | Chemical Communications |
Volume | 59 |
Issue | 55 |
Pagination | 8540-8543 |
Date Published | JUL |
Type of Article | Article |
ISSN | 1359-7345 |
Abstract | The combination of 6-SIDipp center dot AlH3 (1) and 5-IDipp resulted in the ring expansion of 6-NHC, while the five-membered NHC remained unchanged, which was subsequently explained by DFT studies. Besides, the substitution chemistry of 1 was also studied with TMSOTf and I-2, which gave rise to the substitution of a hydride by triflate or iodide ligands. |
DOI | 10.1039/d3cc02063k |
Type of Journal (Indian or Foreign) | Foreign |
Impact Factor (IF) | 4.9 |
Divison category:
Catalysis and Inorganic Chemistry
Central NMR Facility
Physical and Materials Chemistry
Database:
Web of Science (WoS)
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