Synthesis, characterization and single crystal x-ray structures of trifluroacetylacetonate copper(ii) complexes
| Title | Synthesis, characterization and single crystal x-ray structures of trifluroacetylacetonate copper(ii) complexes |
| Publication Type | Journal Article |
| Year of Publication | 2022 |
| Authors | Kumari, N, Bahadur, V, Butcher, RJ, Kumbhar, AA |
| Journal | Journal of Chemical Crystallography |
| Volume | 52 |
| Issue | 4 |
| Pagination | 525-533 |
| Date Published | DEC |
| Type of Article | Article |
| ISSN | 1074-1542 |
| Keywords | Copper(II) complexes, crystal structure, cyclic voltammetry, DABCO, Pyridine, Trifluoroacetylacetone |
| Abstract | {Three Cu(II) complexes of 1,1,1-trifluoroacetylacetonate, viz. [Cu(TFACAC)(2)(MeOH)] (1), [Cu(TFACAC)(2)(py)] (2) and [Cu(TFACAC)(2)(DABCO)] (3) were synthesized and characterized by elemental analysis, IR, UV-Visible spectroscopy and cyclic voltammetry. Structures of complexes 1-3 were established by single crystal X-ray diffraction wherein 1 and 2 adapt square pyramidal geometry. Complex 1 crystallizes in triclinic space group P-(1), with a = 8.5059(6) angstrom |
| DOI | 10.1007/s10870-022-00937-1 |
| Type of Journal (Indian or Foreign) | Foreign |
| Impact Factor (IF) | 0.582 |
Divison category:
Physical and Materials Chemistry
Database:
Web of Science (WoS)