Catalytic hydrogenation of cinnamic acid and salicylic acid

TitleCatalytic hydrogenation of cinnamic acid and salicylic acid
Publication TypeJournal Article
Year of Publication2020
AuthorsShinde, S, Deshpande, RM
JournalAsian Journal of Chemistry
Volume32
Issue2
Pagination339-341
Date PublishedJAN
Type of ArticleArticle
Abstract

Hydrogenation of cinnamic acid and salicylic acid was carried out using 5 %Ru/C, 5 % Pd/C and Ru-Sn/Al2O3 catalyst at 493 K and 6.89 MPa of hydrogen partial pressure. Ru-Sn/Al2O3 catalyst was found to be active for hydrogenation -COOH group to give cinnamyl alcohol. The selectivity to cinnamyl alcohol was low (15 %) as absolute inhibition of C=C bond hydrogenation in cinnamic acid is challenging. 5 %Pd/C catalyst was found to hydrogenate C=C bond and aromatic ring in cinnamic acid. 5 %Ru/C catalyst was found to be least selective catalyst as it hydrogenated C=C bond, aromatic ring and -COOH group in cinnamic acid. Hydrogenation of salicylic acid is not possible at 493 K as decarboxylation of salicylic acid occurs.

DOI10.14233/ajchem.2020.22393
Type of Journal (Indian or Foreign)

Foreign

Impact Factor (IF)

0.336

Divison category: 
Catalysis and Inorganic Chemistry

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