Lithium compound catalyzed deoxygenative hydroboration of primary, secondary and tertiary amides
| Title | Lithium compound catalyzed deoxygenative hydroboration of primary, secondary and tertiary amides |
| Publication Type | Journal Article |
| Year of Publication | 2021 |
| Authors | Bisai, MKumar, Gour, K, Das, T, Vanka, K, Sen, SS |
| Journal | Dalton Transactions |
| Volume | 50 |
| Issue | 7 |
| Pagination | 2354-2358 |
| Date Published | FEB |
| Type of Article | Article |
| ISSN | 1477-9226 |
| Abstract | A selective and efficient route for the deoxygenative reduction of primary to tertiary amides to corresponding amines has been achieved with pinacolborane (HBpin) using simple and readily accessible 2,6-di-tert-butyl phenolate lithium center dot THF (1a) as a catalyst. Both experimental and DFT studies provide mechanistic insight. |
| DOI | 10.1039/d1dt00364j |
| Type of Journal (Indian or Foreign) | Foreign |
| Impact Factor (IF) | 4.390 |
Divison category:
Catalysis and Inorganic Chemistry
Physical and Materials Chemistry
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