Microstructural differences between Viscose and Lyocell revealed by in-situ studies of wet and dry fibers

TitleMicrostructural differences between Viscose and Lyocell revealed by in-situ studies of wet and dry fibers
Publication TypeJournal Article
Year of Publication2020
AuthorsSharma, A, Thakre, S, Kumaraswamy, G
JournalCellulose
Volume27
Issue3
Pagination1195-1206
Date PublishedFEB
Type of ArticleArticle
ISSN0969-0239
Keywordsbirefringence, Crystal-amorphous orientation, In-situ WAXD, Regenerated cellulose
Abstract

Regenerated cellulose fibers manufactured using Lyocell and Viscose processes exhibit differences in their structural response to mechanical deformation. Here, we study the effect of stretching and stress relaxation on the orientation of crystal and amorphous phases. Our results show that on stretching, orientation in both crystal and amorphous phases increases linearly with strain, correlating with the increase in stress and with the stretching of the crystalline unit cell along the c-axis. On holding after stretching to a particular strain, the stress relaxes logarithmically in time, correlating with a decrease in the strain along the c-axis of the crystal unit cell. The stress relaxation is also correlated with a logarithmic increase in amorphous orientation, while crystalline orientation stays constant. We attribute the stress development during stretching to deformation of the crystal unit cell, while crystal reorientation in the fiber direction results in increase in the crystalline orientation parameter. On holding the fiber at a fixed total strain, the stress relaxes as strain is transferred from crystal to amorphous regions. Thus, the strain on the unit cell c-axis decreases and amorphous orientation increases. There are quantitative differences between the rate of increase in amorphous phase orientation during stress relaxation for Lyocell and Viscose fibers. For dry fibers, Lyocell shows a slower increase in orientation during stress relaxation. On wetting the fibers, their structural response changes qualitatively. We combine wide angle x ray diffraction and birefringence experiments with our model to infer that that on stretching the wet fiber, the crystalline phase is neither strained nor oriented. However, orientation develops in the amorphous phase. During stress relaxation in wet condition, Lyocell fibers shows a faster increase in amorphous orientation than Viscose fibers, in line with the comparison of relaxation time spectra for wet Viscose and Lyocell fibers. Graphic abstract

DOI10.1007/s10570-019-02863-6
Type of Journal (Indian or Foreign)

Foreign

Impact Factor (IF)

4.210

Divison category: 
Polymer Science & Engineering

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