Aromatic amine passivated TiO2 for dye-sensitized solar cells (DSSC) with similar to 9.8% efficiency

TitleAromatic amine passivated TiO2 for dye-sensitized solar cells (DSSC) with similar to 9.8% efficiency
Publication TypeJournal Article
Year of Publication2020
AuthorsKumar, TRNaveen, Yuvaraj, S, Kavitha, P, Sudhakar, V, Krishnamoorthy, K, Neppolian, B
JournalSolar Energy
Volume201
Pagination965-971
Date PublishedMAY
Type of ArticleArticle
ISSN0038-092X
KeywordsAromatic amines, DSSC, Electron injection, lifetime, Scattering layer, TiO2
Abstract

In this work, the efficiency of dye-sensitized solar cells (DSSC) was improved by capping TiO2 with simple aromatic amines as a complexing agent. The aromatic amines, aniline and o-phenylenediamine capped TiO2 composites were synthesized via hydrothermal route and used as scattering layer in dye-sensitized solar cell (DSSC). Markedly, the maximum photo-conversion efficiency of 9.84% was achieved with o-phenylenediamine capped-TiO2 composite as o-phenylenediamine capped-TiO2 showed higher reflectivity than the pristine TiO2, which is highly beneficial for reflecting the photons back to photoanode. In addition, the average life time of carriers in o-phenylenediamine capped-TiO2 was found to be 9.8 ms, which was 2 times higher than the pristine TiO2 (4.29 ms).

DOI10.1016/j.solener.2020.03.077
Type of Journal (Indian or Foreign)

Foreign

Impact Factor (IF)

4.608

Divison category: 
Polymer Science & Engineering

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