Manganese-catalyzed direct C-C coupling of -C-H bonds of amides and esters with alcohols via hydrogen autotransfer
| Title | Manganese-catalyzed direct C-C coupling of -C-H bonds of amides and esters with alcohols via hydrogen autotransfer |
| Publication Type | Journal Article |
| Year of Publication | 2019 |
| Authors | Rana, J, Gupta, V, Balaraman, E |
| Journal | Dalton Transactions |
| Volume | 48 |
| Issue | 21 |
| Pagination | 7094-7099 |
| Date Published | JUN |
| Type of Article | Article |
| ISSN | 1477-9226 |
| Abstract | Herein we report an efficient manganese-catalyzed C-alkylation of unactivated amides and tert-butyl acetate using alcohols as alkylating agents. This elegant approach exhibits a broad substrate scope providing the C-C coupled products of amides via a hydrogen auto-transfer strategy using aryl, heteroaryl, and aliphatic alcohols. |
| DOI | 10.1039/c8dt05020a |
| Type of Journal (Indian or Foreign) | Foreign |
| Impact Factor (IF) | 4.052 |
Divison category:
Organic Chemistry