Selective aerobic oxidation of alcohols over Au-Pd/sodium titanate nanotubes

TitleSelective aerobic oxidation of alcohols over Au-Pd/sodium titanate nanotubes
Publication TypeJournal Article
Year of Publication2015
AuthorsNepak, D, Darbha, S
JournalCatalysis Communications
Volume58
Pagination149-153
Date PublishedJAN
Type of ArticleArticle
ISSN1566-7367
Keywordsaerobic oxidation, Alcohol, Bimetallic Au-Pd catalyst, Sodium titanate nanotubes, TiO2
Abstract

catalytic application of Au-Pd nanoparticles supported on sodium titanate nanotubes (NaTNTs) for liquid-phase aerobic oxidation of alcohols is reported, for the first time. This reaction occurs at 80-120 degrees C, 1 atm and solvent-/alkali-free conditions yielding the corresponding carbonyls in high selectivity. This catalyst was reusable and found to be more active/selective than the corresponding monometallic Au and Pd catalysts and Au-Pd/TiO2. Higher dispersion, smaller particle size and higher amount of electron density at gold are the causes for the superior activity of Au-Pd/NaTNT catalyst. (C) 2014 Elsevier B.V. All rights reserved.

DOI10.1016/j.catcom.2014.09.018
Type of Journal (Indian or Foreign)Foreign
Impact Factor (IF)3.389
Divison category: 
Catalysis and Inorganic Chemistry

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