Present investigation deal with the facile synthesis of Co9Se8 nanoparticles (NPs) and their application as the potential anode for lithium-ion battery (LIB). The primary size of the Co9Se8 NPs can be achieved between 10 similar to 25 nm while the secondary cluster size ranging from 150 similar to 200 nm as observed by transmission electron microscope (TEM). The specific capacity of Co9Se8 NPs LIB anode can reach around similar to 610 mAhg(-1) during charging (lithium ion released from Co9Se8 nanoparticles), and -730 mAhg(-1) during discharging (lithium ion intercalated) at an applied current density of similar to 100 mAg(-1). These values are significantly higher than that of the commercial graphite anode (theoretical capacity similar to 372 mAhg(-1)). The irreversibility of Co9Se8 anode (similar to 15%) is also significantly lower than that of most metal oxides and silicon-based anodes (irreversibility ranging between 30 similar to 50% or higher for Si). The reason for superior specific capacity and low irreversibility compared to metal oxides and silicon-based materials could be owing to the stable nano-cluster size which help to reduce the diffusion path and internal resistance to lithium ion.