Simple cobalt(II) chloride catalyzed N-alkylation of amines with alcohols

TitleSimple cobalt(II) chloride catalyzed N-alkylation of amines with alcohols
Publication TypeJournal Article
Year of Publication2017
AuthorsMidya, SP, Mondal, A, Begum, A, Balaraman, E
JournalSynthesis-Stuttgart
Volume49
Start Page3957-3961
Issue17
Pagination3957-3961
Date PublishedSEP
Type of ArticleJournal Article
ISSN0039-7881
Keywords(Hetero)Aromatic Amines, Alcohols, Amination, amines, Anilines, Aromatic-amines, Cobalt Catalysis, Dehydrogenation Borrowing Hydrogen, Efficient Catalysts, Hydrogen Autotransfer, Iridium, N-alkylation, Pincer-complex, Secondary Alcohols, Selective Alkylation
Abstract

A facile cobalt-catalyzed N-alkylation of amines with alcohols using inexpensive, commercially available CoCl2 center dot 6H(2)O is reported. Employing this readily available cobalt catalyst, a variety of amines with wide functional group tolerance were selectively alkylated under benign conditions.

DOI10.1055/s-0036-1589064
Type of Journal (Indian or Foreign)

Foreign

Impact Factor (IF)

2.652

Divison category: 
Catalysis and Inorganic Chemistry

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