Metal free mild and selective aldehyde cyanosilylation by a neutral penta-coordinate silicon compound
| Title | Metal free mild and selective aldehyde cyanosilylation by a neutral penta-coordinate silicon compound |
| Publication Type | Journal Article |
| Year of Publication | 2017 |
| Authors | Swamy, VSVSN, Bisai, MKumar, Das, T, Sen, SS |
| Journal | Chemical Communications |
| Volume | 53 |
| Issue | 51 |
| Date Published | JUN |
| Abstract | This study demonstrates the preparation and structural characterization of a Si(IV) hydride (PhC(NtBu)(2)SiH(CH3)Cl) (1) and its use as a catalyst for the cyanosilylation of a variety of aldehydes. Compound 1 represents the first neutral penta-coordinate silicon(IV) species that catalyzes cyanosilylation of aldehydes under mild conditions. |
| DOI | 10.1039/c7cc03948d |
| Type of Journal (Indian or Foreign) | Foreign |
| Impact Factor (IF) | 6.567 |
Divison category:
Catalysis and Inorganic Chemistry
Physical and Materials Chemistry
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