Strikingly diverse reactivity of structurally identical silylene and stannylene
| Title | Strikingly diverse reactivity of structurally identical silylene and stannylene |
| Publication Type | Journal Article |
| Year of Publication | 2017 |
| Authors | Parvin, N, Dasgupta, R, Pal, S, Sen, SS, Khan, S |
| Journal | Dalton Transactions |
| Volume | 46 |
| Issue | 20 |
| Pagination | 6528-6532 |
| Date Published | MAY |
| Abstract | The reactivity of structurally identical silylene and stannylene [PhC(NtBu)(2)EN(SiMe3)(2)] (E = Si (1) and Sn (2)) towards coinage metals has been explored. While 1 has the propensity to form an adduct with coinage metals (4 and 5), 2 undergoes a ligand exchange reaction with copper halides and silver triflate leading to PhC(NtBu) 2SnX (X = Br (6), Cl (7), and OSO2CF3 (8)) with concomitant formation of [M{N(SiMe3) (2)}] (M = Cu, Ag). However, with AgSbF6 both 1 and 2 led to ion pairs, 9(+) .SbF(6)(-)and 10(+) . SbF(6)(-)displaying weaker Ag center dot center dot center dot center dot F interactions in the latter. |
| DOI | 10.1039/c7dt01055a |
| Type of Journal (Indian or Foreign) | Foerign |
| Impact Factor (IF) | 4.177 |
Divison category:
Catalysis and Inorganic Chemistry
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