F and CF3 substituted solution processable oligo para-phenylenevinylene for ambipolar and hole-transporting organic field effect transistors

TitleF and CF3 substituted solution processable oligo para-phenylenevinylene for ambipolar and hole-transporting organic field effect transistors
Publication TypeJournal Article
Year of Publication2016
AuthorsChini, MKumar, Das, C, Chatterjee, S
JournalChemical Physics Letters
Volume657
Pagination26-32
Date PublishedJUL
AbstractWe have synthesized benzotrifluoromethyl group substituted para-phenylenevinylene oligomer (denoted as PI) and a cooligomer (denoted as PII) by Gilch polymerization route. The ambipolar field-effect transistor (FET) material PI shows hole and electron mobility 1 x 10 (4) cm(2) V (1) s (1) and 2 x 10 (5) cm(2) V (1) s (1) respectively. PII shows only hole mobility as high as 0.05 cm(2) V (1) s (1) as p-type material. This work highlights the progress of hole-transporting as well as ambipolar material for para-phenylenevinylene derivatives. The results are enlightened on the basis of presence of electronegative substituents and structural modification of the oligomer backbone. (C) 2016 Elsevier B.V. All rights reserved.
DOI10.1016/j.cplett.2016.05.042
Type of Journal (Indian or Foreign)Foreign
Impact Factor (IF)1.86
Divison category: 
Polymer Science & Engineering

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