Synthesis of functionalized β-keto arylthioethers by the aryne induced [2,3] Stevens rearrangement of allylthioethers
| Title | Synthesis of functionalized β-keto arylthioethers by the aryne induced [2,3] Stevens rearrangement of allylthioethers |
| Publication Type | Journal Article |
| Year of Publication | 2017 |
| Authors | Thangaraj, M, Gaykar, RN, Roy, T, Biju, AT |
| Journal | Journal of Organic Chemistry |
| Volume | 82 |
| Start Page | 4470–4476 |
| Issue | 8 |
| Pagination | 4470–4476 |
| Date Published | MAR |
| Type of Article | Article |
| Abstract | A mild and transition-metal-free synthesis of β-keto arylthioethers has been developed by the aryne triggered [2,3] Stevens rearrangement of allylthioethers. The key sulfur ylide intermediate for the rearrangement was formed by the S-arylation of allylthioethers with arynes generated from 2-(trimethylsilyl)aryl triflates using CsF. Later, the reaction products are converted into valuable heterocycles in two steps. |
| DOI | 10.1021/acs.joc.7b00479 |
| Type of Journal (Indian or Foreign) | Foreign |
| Impact Factor (IF) | 4.785 |
Divison category:
Organic Chemistry