[3+2]-Annulation of platinum-bound azomethine ylides with distal C[double bond, length as m-dash]C bonds of N-allenamides
| Title | [3+2]-Annulation of platinum-bound azomethine ylides with distal C[double bond, length as m-dash]C bonds of N-allenamides |
| Publication Type | Journal Article |
| Year of Publication | 2017 |
| Authors | Chakrabarty, I, Inamdar, SM, Akram, MO, Gade, AB, Banerjee, S, Bera, S, Patil, NT |
| Journal | Chemical Communications |
| Volume | 53 |
| Issue | 1 |
| Pagination | 196-199 |
| Date Published | JAN |
| Type of Article | Article |
| Abstract | A Pt-catalyzed, highly regioselective reaction between N-allenamides and imino-alkynes leading to pyrrolo[1,2-a] indoles is described. This represents the first example of [3+2]-annulation of Pt-bound azomethine ylides with the distal CQC bond of N-allenamides. The mechanism of the reaction was established by computational studies. |
| DOI | 10.1039/c6cc07874e |
| Type of Journal (Indian or Foreign) | Foreign |
| Impact Factor (IF) | 6.567 |
Divison category:
Organic Chemistry
Physical and Materials Chemistry