O-2-Naphthyl diphenylthiophosphinate
| Title | O-2-Naphthyl diphenylthiophosphinate |
| Publication Type | Journal Article |
| Year of Publication | 2007 |
| Authors | Mague, JT, Punji, B, Ganesamoorthy, C, Balakrishna, MS |
| Journal | Acta Crystallographica Section E-Crystallographic Communications |
| Volume | 63 |
| Issue | 12 |
| Pagination | 4644 |
| Date Published | DEC |
| Type of Article | Article |
| Abstract | The molecule of the title compound, C10H7OP(S)(C6H5)2 or C22H17OPS, exhibits distorted tetrahedral geometry about the P atom. The P=S bond of 1.9355 (4) Å is shorter than that found in Ph3P=S [1.950 (3) Å] because the replacement of one carbon on phosphorus by oxygen increases the effective electronegativity of the P atom, thereby enhancing pπ–dπ back-donation from a lone-pair orbital of the S atom. |
| DOI | 10.1107/S1600536807056127 |
| Funding Agency | Council of Scientific & Industrial Research (CSIR) - India |
| Type of Journal (Indian or Foreign) | Foreign |
| Impact Factor (IF) | 0.21 |
Divison category:
Organic Chemistry