Carbon-nitrogen bond-forming reactions of dialkyl azodicarboxylate: a promising synthetic strategy

TitleCarbon-nitrogen bond-forming reactions of dialkyl azodicarboxylate: a promising synthetic strategy
Publication TypeJournal Article
Year of Publication2008
AuthorsNair, V, Biju, AT, Mathew, SC, Pattoorpadi, BBabu
JournalChemistry an Asian Journal
Volume3
Issue5
Pagination810–820
Date PublishedMAY
Type of ArticleArticle
Keywordsamination reactions; azodicarboxylates; C[BOND]N bond formation; heterocycles; Huisgen zwitterion
Abstract

Azodicarboxylates have found applications in electrophilic amination reactions and in pericyclic reactions. The nucleophilic trigger in Mitsunobu reactions, that is, the zwitterion formed from triphenylphosphine and dialkyl azodicarboxylate, has been utilized recently in various heterocyclic constructions. This Focus Review summarizes the potential utility of azodicarboxylates in various carbon–nitrogen bond-forming reactions.

DOI10.1002/asia.200700341
Funding Agency

Council of Scientific & Industrial Research (CSIR) - India

Type of Journal (Indian or Foreign)Foreign
Impact Factor (IF)4.14
Divison category: 
Organic Chemistry