Eco-friendly synthesis of epichlorohydrin catalyzed by titanium silicate (TS-1) molecular sieve and hydrogen peroxide

TitleEco-friendly synthesis of epichlorohydrin catalyzed by titanium silicate (TS-1) molecular sieve and hydrogen peroxide
Publication TypeJournal Article
Year of Publication2007
AuthorsPandey, RKumar, Kumar, R
JournalCatalysis Communications
Volume8
Issue3
Pagination379-382
Date PublishedMAR
Type of ArticleArticle
ISSN1566-7367
Keywordsallyl chloride, epichlorohydrin, epoxidation, heterogeneous catalysis, selectivity, titanium silicalite-1
Abstract

In a mixed solvent system of acetonitrile and methanol, titanium silicate molecular sieve, TS-1, having MFI topology, efficiently catalyses the epoxidation of allyl chloride to the corresponding epichlorohydrin in excellent yields using dilute hydrogen peroxide (45%) as an oxidizing agent. (c) 2006 Elsevier B.V. All rights reserved.

DOI10.1016/j.catcom.2006.07.007
Type of Journal (Indian or Foreign)Foreign
Impact Factor (IF)3.389
Divison category: 
Catalysis and Inorganic Chemistry