Synthesis and characterization of hindered amine light stabilizers based on end functionalization of polypropylene

TitleSynthesis and characterization of hindered amine light stabilizers based on end functionalization of polypropylene
Publication TypeJournal Article
Year of Publication2007
AuthorsK. Reddy, R, Kumar, B, Rana, S, Tevtia, AK, Singh, RP
JournalJournal of Applied Polymer Science
Volume104
Issue3
Pagination1596-1602
Date PublishedMAY
Type of ArticleArticle
ISSN0021-8995
Keywordsend functionalization, functionalization of polymers, polymeric HALS, polypropylene, vinylidine and photostabilization
Abstract

A polymeric hindered amine light stabilizer (HALS), where HALS moiety was attached at the terminal end of the polypropylene chain via end-functionalized vinylidine PP through simple organic reactions, was synthesized. It comprises the synthesis of vinylidine-terminated polypropylene by using Cp2ZrCl2/MAO as catalyst system and epoxidation of vinylidene polypropylene. The final product was synthesized by carrying out the reaction between epoxy end functionalized polypropylene and 4-amino-2,2,6,6-tetrametyl piperidine. The final product was characterized by using H-1 NMR, C-13 NMR, and FT-IR spectra. Functionality was calculated by using vapor phase osmometry and H-1 NMR. The solubility and diffusion coefficient of the product were calculated and also its stabilization performance was checked. (c) 2007 Wiley Periodicals, Inc.

DOI10.1002/app.25745
Type of Journal (Indian or Foreign)Foreign
Impact Factor (IF)1.866
Divison category: 
Polymer Science & Engineering