Enantioselective synthesis of tarchonanthuslactone using proline-catalyzed asymmetric alpha-aminooxylation

TitleEnantioselective synthesis of tarchonanthuslactone using proline-catalyzed asymmetric alpha-aminooxylation
Publication TypeJournal Article
Year of Publication2007
AuthorsGeorge, S, Sudalai, A
JournalTetrahedron-Asymmetry
Volume18
Issue8
Pagination975-981
Date PublishedMAY
Type of ArticleArticle
ISSN0957-4166
Abstract

A practical enantio selective synthesis of tarchonanthuslactone 1, an important natural product with a polyol unit, is described. The sequence of synthetic reactions involves proline-catalyzed alpha-aminooxylation and iodine-induced electrophilic cyclization as the chiral inducing steps. (c) 2007 Elsevier Ltd. All rights reserved.

DOI10.1016/j.tetasy.2007.04.008
Type of Journal (Indian or Foreign)Foreign
Impact Factor (IF)2.108
Divison category: 
Chemical Engineering & Process Development