Gold(I) catalyzed [1,3] O -> C rearrangement of benzylvinyl ethers

TitleGold(I) catalyzed [1,3] O -> C rearrangement of benzylvinyl ethers
Publication TypeJournal Article
Year of Publication2016
AuthorsKona, CNaidu, Patil, MN, Ramana, CV
JournalOrganic Chemistry Frontiers
Volume3
Issue4
Pagination453-456
Date PublishedJAN
ISSN2052-4129
Abstract

A simple procedure for the preparation of 3-(hetero) arylpropionaldehydes has been developed employing a gold-catalyzed [1,3]-rearrangement of vinyl ethers. Using this protocol, Canthoxal, an aromatic aldehyde used in perfumery, has been prepared on a gram scale.

DOI10.1039/c5qo00397k
Type of Journal (Indian or Foreign)

Foreign

Impact Factor (IF)4.693
Divison category: 
Organic Chemistry