Synthesis, characterization and catalytic potentials of polymer anchored copper(II), oxovanadium(IV) and dioxomolybdenum(VI) complexes of 2-(alpha-hydroxymethyl)benzimidazole

TitleSynthesis, characterization and catalytic potentials of polymer anchored copper(II), oxovanadium(IV) and dioxomolybdenum(VI) complexes of 2-(alpha-hydroxymethyl)benzimidazole
Publication TypeJournal Article
Year of Publication2005
AuthorsMaurya, MR, Sikarwar, S, Joseph, T, Manikandan, P, Halligudi, SB
JournalReactive & Functional Polymers
Volume63
Issue1
Pagination71-83
Date PublishedMAR
Type of ArticleArticle
ISSN1381-5148
Keywords2-(alpha-hydroxymethyl)benzimidazole, oxidation of styrene and ethyl benzene, oxidative bromination of salicylaldehyde, polymer anchored-complexes
Abstract

{2-(alpha-Hydroxymethyl)benzimidazole (Hhmbmz) has been covalently anchored to chloromethylated polystyrene cross-linked with 5% divinylbenzene. This chelating resin reacts with cupric acetate, vanadyl sulphate and [MoO(2)-(acac)(2)] (Hacac = acetylacetone) in presence of Hhmbmz to give complexes PS-[Cu(hmbmz)(2)], PS-[VO(hmbmz)(2)] and PS-[MoO(2)(hmbmz)(2)] (where

DOI10.1016/j.reactfunctpolym.2005.02.008
Type of Journal (Indian or Foreign)

Foreign

Impact Factor (IF)2.725
Divison category: 
Catalysis and Inorganic Chemistry