Efficient stereoselective synthesis of (2S,4S,5R)-(-)- and (2R,4R,5S)-(+)-bulgecinine
Title | Efficient stereoselective synthesis of (2S,4S,5R)-(-)- and (2R,4R,5S)-(+)-bulgecinine |
Publication Type | Journal Article |
Year of Publication | 2005 |
Authors | Chavan, SP, Praveen, C, Sharma, P, Kalkote, UR |
Journal | Tetrahedron Letters |
Volume | 46 |
Issue | 3 |
Pagination | 439-441 |
Date Published | JAN |
Type of Article | Article |
ISSN | 0040-4039 |
Abstract | A short synthetic route to (-)-and (+)-bulgecinine, the amino acid moiety of the bulgecins was achieved from the readily available nonchiral pool starting material cis-2-butene-1,4-diol in which a Claisen orthoester rearrangement and a Sharpless asymmetric dihydroxylation were used as the key steps. (C) 2004 Elsevier Ltd. All rights reserved. |
DOI | 10.1016/j.tetlet.2004.11.101 |
Type of Journal (Indian or Foreign) | Foreign |
Impact Factor (IF) | 2.347 |
Divison category:
Organic Chemistry