NalO(4)/LiBr-mediated diastereoselective dihydroxylation of olefins: a catalytic approach to the prevost-woodward reaction
| Title | NalO(4)/LiBr-mediated diastereoselective dihydroxylation of olefins: a catalytic approach to the prevost-woodward reaction |
| Publication Type | Journal Article |
| Year of Publication | 2005 |
| Authors | Emmanuvel, L, Shaikh, TMA, Sudalai, A |
| Journal | Organic Letters |
| Volume | 7 |
| Issue | 22 |
| Pagination | 5071-5074 |
| Date Published | OCT |
| Type of Article | Article |
| ISSN | 1523-7060 |
| Abstract | LlBr catalyzes efficiently the dihydroxylation of alkenes to afford syn and anti diols with excellent diastereoselectivity depending upon the use of NaIO4 (30 mol %) or Phl(OAc)(2) (1 equiv), respectively, as the oxidants. The oxidation of non-benzylic halides has been achieved for the first time to afford the corresponding diols in excellent yields. |
| DOI | 10.1021/ol052080n |
| Type of Journal (Indian or Foreign) | Foreign |
| Impact Factor (IF) | 6.732 |
Divison category:
Chemical Engineering & Process Development