Hydrophobic effects are dominant over secondary orbital interactions for a simple Diels-Alder reaction in salt solutions

TitleHydrophobic effects are dominant over secondary orbital interactions for a simple Diels-Alder reaction in salt solutions
Publication TypeJournal Article
Year of Publication2006
AuthorsSarma, D, Kumar, A
JournalOrganic Letters
Volume8
Issue10
Pagination2199-2202
Date PublishedMAY
Type of ArticleArticle
ISSN1523-7060
Abstract

The stereoselectivity ratios for a Diels-Alder reaction between cyclopentadiene with methyl trans-crotonate carried out in salt solutions demonstrate the dominance of hydrophobic effects over secondary orbital interactions.

DOI10.1021/ol060741q
Funding Agency

Council of Scientific & Industrial Research (CSIR) - India

Type of Journal (Indian or Foreign)

Foreign

Impact Factor (IF)6.732
Divison category: 
Physical and Materials Chemistry