Short synthesis of (+)-harzialactone A and (R)-(+)-4-hexanolide via proline-catalyzed sequential alpha-aminooxylation and horner-wadsworth-emmons olefination of aldehydes
Title | Short synthesis of (+)-harzialactone A and (R)-(+)-4-hexanolide via proline-catalyzed sequential alpha-aminooxylation and horner-wadsworth-emmons olefination of aldehydes |
Publication Type | Journal Article |
Year of Publication | 2007 |
Authors | Kotkar, SP, Suryavanshi, GS, Sudalai, A |
Journal | Tetrahedron-Asymmetry |
Volume | 18 |
Issue | 15 |
Pagination | 1795-1798 |
Date Published | AUG |
Type of Article | Article |
ISSN | 0957-4166 |
Keywords | core-shell nanoparticles, Gold, HRTEM, interfacial seeded growth, Silver, XPS |
Abstract | {In melts, ring polymers assume more compact conformations compared to linear chains with the same degree of polymerization N-r, i.e. R-r similar to N-r(nu) with nu approximate to 0.4, where R-r is the radius of gyration. Upon gradually substituting some of the ring polymers with linear chains, the ring molecules swell. In the limit of infinite dilution, their size scales as R-r similar to N-r(0.5). We present a scaling argument based on the blob model to capture this transition. Ring-linear blends are modeled as a semidilute solution of ring polymers in a theta-solvent consisting of linear chains. The model predicts that the size of the ring polymer remains unchanged up to the overlap concentration c(r)(* |
DOI | 10.1016/j.tetasy.2007.07.031 |
Type of Journal (Indian or Foreign) | Foreign |
Impact Factor (IF) | 2.108 |